Sn(IV)-corroles reversibly bind carboxylates in the axial position

Research output: Contribution to journalJournal articleResearchpeer-review

We present the synthesis of Sn(IV)-corrole complexes that bind to carboxylate moieties reversibly, via axial ligation. The systems have been predominantly characterized using 1H NMR spectroscopy, X-ray crystallography, and MALDI mass spectrometry. The dynamic nature of the Sn(IV)-O2CR bond has been studied in solution using 2D-NMR spectroscopy.

Original languageEnglish
JournalJournal of Porphyrins and Phthalocyanines
Volume27
Issue number07n10
ISSN1088-4246
DOIs
Publication statusPublished - 2023

Bibliographical note

Publisher Copyright:
© 2023 World Scientific Publishing Company.

    Research areas

  • carboxylate, corrole, exchange, NMR, Sn, supramolecular, x-ray

ID: 361690146