One-dimensional coordination polymers of [Co3(dpa)4]2+ and [MF6]2- (M = ReIV, ZrIV and SnIV)

One-dimensional coordination polymers of [Co₃(dpa)₄]²⁺ and [MF₆]^2- (M = Re^IV, Zr^IV and Sn^IV)

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Bulicanu_2015_One-dimensional_coordination_polymers
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Vladimir Bulicanu
Kasper Steen Pedersen
Mathieu Rouzières
Bendix, Jesper
Pierre Dechambenoit
Rodolphe Clérac
Elizabeth A. Hillard

One-dimensional coordination polymers of alternating metal-metal bonded trinuclear [Co₃(dpa)₄]²⁺ (dpa = the anion of 2,2'-dipyridylamine) building blocks and [ReF₆]^2- (1), [ZrF₆]^2- (2) or [SnF₆]^2- (3) linkers have been self-assembled and crystallographically characterized. Magnetic measurements reveal a significant ferromagnetic coupling (J/k_B = +9.9 K) between S = 1/2 {Co₃⁶⁺} and S = 3/2 Re^IV magnetic sites through a single, unsupported fluoride bridge in 1.

Original language	English
Journal	Chemical Communications
Volume	51
Issue number	100
Pages (from-to)	17748-17751
Number of pages	4
ISSN	1359-7345
DOIs	https://doi.org/10.1039/c5cc06704a
Publication status	Published - 2015

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