Microwave-assisted McMurry polymerization utilizing low-valent titanium for the synthesis of poly 2,6-[1,5-bis(dodecyloxy)naphthylene vinylene] (PNV)
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Poly 2,6-[1,5-bis(dodecyloxy)naphthylene vinylene] is synthesized by microwave-assisted McMurry polymerization utilizing low-valent titanium generated from titanium tetrachloride and zinc. The obtained polymer is fluorescent with an average molecular weight of approximately 65,000 g/mol and a polydispersity of M-w/M-n approximate to 3. Absorption and fluorescence spectroscopy in solution and on spin-cast thin films reveal that the bis-alkoxy substituted PNV has a short effective Conjugation length but a quite efficient exciton migration. (C) 2009 Elsevier Ltd. All rights reserved.
Original language | English |
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Journal | Tetrahedron Letters |
Volume | 50 |
Issue number | 52 |
Pages (from-to) | 7374-7378 |
Number of pages | 5 |
ISSN | 0040-4039 |
DOIs | |
Publication status | Published - 2009 |
ID: 16158187