Catalytic stereospecific O-glycosylation

Research output: Contribution to journalJournal articleResearchpeer-review

A new simple protocol, using TMSNTf2 or Tf2NH as the catalyst, for the activation of trichloroacetimidate donors is described. This O-glycosylation proceeds with stereospecific inversion of the donor configuration. The scope of the protocol has been investigated using common glycosyl donors reacting with simple alcohols as well as sugar acceptors
Original languageEnglish
JournalChemical Communications
Volume53
Issue number12
Pages (from-to)2040-2043
Number of pages4
ISSN1359-7345
DOIs
Publication statusPublished - 2017

ID: 176368109