Atmospheric chemistry of methoxyflurane (CH3OCF2CHCl2): Products and mechanisms

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Standard

Atmospheric chemistry of methoxyflurane (CH3OCF2CHCl2) : Products and mechanisms. / Hass, S. A.; Sulbaek Andersen, M. P.; Nielsen, O. J.

In: Chemical Physics Letters, Vol. 740, 137052, 02.2020.

Research output: Contribution to journal › Journal article › Research › peer-review

Harvard

Hass, SA, Sulbaek Andersen, MP & Nielsen, OJ 2020, 'Atmospheric chemistry of methoxyflurane (CH3OCF2CHCl2): Products and mechanisms', Chemical Physics Letters, vol. 740, 137052. https://doi.org/10.1016/j.cplett.2019.137052

APA

Hass, S. A., Sulbaek Andersen, M. P., & Nielsen, O. J. (2020). Atmospheric chemistry of methoxyflurane (CH3OCF2CHCl2): Products and mechanisms. Chemical Physics Letters, 740, [137052]. https://doi.org/10.1016/j.cplett.2019.137052

Vancouver

Hass SA, Sulbaek Andersen MP, Nielsen OJ. Atmospheric chemistry of methoxyflurane (CH3OCF2CHCl2): Products and mechanisms. Chemical Physics Letters. 2020 Feb;740. 137052. https://doi.org/10.1016/j.cplett.2019.137052

Author

Hass, S. A. ; Sulbaek Andersen, M. P. ; Nielsen, O. J. / Atmospheric chemistry of methoxyflurane (CH3OCF2CHCl2) : Products and mechanisms. In: Chemical Physics Letters. 2020 ; Vol. 740.

Bibtex

@article{988d335976034851ae3a66dd41490fbe,
title = "Atmospheric chemistry of methoxyflurane (CH3OCF2CHCl2): Products and mechanisms",
abstract = "Long pathlength/FTIR smog chamber techniques were used to determine the Cl atom initiated atmospheric oxidation mechanisms for methoxyflurane (CH3OCF2CHCl2) in 700 Torr of air or O2 diluent at 296 K. The oxidation of CH3OCF2CHCl2 in both air and O2 diluent gave one primary carbonyl-containing product in approximately 100% yield and one secondary bi-carbonyl product in addition to COF2 and COCl2, the latter two both with initial molar yields of 2 ± 1%. A mechanism is proposed for the oxidation of methoxyflurane which explains the observed product distribution. IR spectra for HC(O)OCF2CHCl2 and HC(O)OCF2C(O)Cl are calculated and reported.",
author = "Hass, {S. A.} and {Sulbaek Andersen}, {M. P.} and Nielsen, {O. J.}",
year = "2020",
month = feb,
doi = "10.1016/j.cplett.2019.137052",
language = "English",
volume = "740",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Atmospheric chemistry of methoxyflurane (CH3OCF2CHCl2)

T2 - Products and mechanisms

AU - Hass, S. A.

AU - Sulbaek Andersen, M. P.

AU - Nielsen, O. J.

PY - 2020/2

Y1 - 2020/2

N2 - Long pathlength/FTIR smog chamber techniques were used to determine the Cl atom initiated atmospheric oxidation mechanisms for methoxyflurane (CH3OCF2CHCl2) in 700 Torr of air or O2 diluent at 296 K. The oxidation of CH3OCF2CHCl2 in both air and O2 diluent gave one primary carbonyl-containing product in approximately 100% yield and one secondary bi-carbonyl product in addition to COF2 and COCl2, the latter two both with initial molar yields of 2 ± 1%. A mechanism is proposed for the oxidation of methoxyflurane which explains the observed product distribution. IR spectra for HC(O)OCF2CHCl2 and HC(O)OCF2C(O)Cl are calculated and reported.

AB - Long pathlength/FTIR smog chamber techniques were used to determine the Cl atom initiated atmospheric oxidation mechanisms for methoxyflurane (CH3OCF2CHCl2) in 700 Torr of air or O2 diluent at 296 K. The oxidation of CH3OCF2CHCl2 in both air and O2 diluent gave one primary carbonyl-containing product in approximately 100% yield and one secondary bi-carbonyl product in addition to COF2 and COCl2, the latter two both with initial molar yields of 2 ± 1%. A mechanism is proposed for the oxidation of methoxyflurane which explains the observed product distribution. IR spectra for HC(O)OCF2CHCl2 and HC(O)OCF2C(O)Cl are calculated and reported.

U2 - 10.1016/j.cplett.2019.137052

DO - 10.1016/j.cplett.2019.137052

M3 - Journal article

AN - SCOPUS:85077345166

VL - 740

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

M1 - 137052

ER -

ID: 235092689