The mixed-valent (μ-nitrido)-dimanganese complex anion [(CN)5Mn(v)(μ- N)Mn(II)(CN)5]6-
Research output: Contribution to journal › Journal article › Research › peer-review
Localized valencies are displayed by the Mn(v)Mn(II) complex ion 1. This is the key finding from X-ray structure analysis, as well as vibrational and EPR spectroscopic investigations on 1 obtained by the reaction of manganese(II) and [Mn(v)(N)(CN)5]3- salts in aqueous 1M NaCN solution. Remarkably, the asymmetry is induced by the nitrogen atom bridge.
| Original language | English |
|---|---|
| Journal | Angewandte Chemie - International Edition |
| Volume | 38 |
| Issue number | 18 |
| Pages (from-to) | 2766-2768 |
| Number of pages | 3 |
| ISSN | 1433-7851 |
| Publication status | Published - 17 Sep 1999 |
- Manganese, Mixed-valent compounds, Multiple bonds, Nitrides
Research areas
ID: 240004097