Structural, electrochemical, and photophysical properties of gallium(III) 5, 10, 15-tris(pentafluorophenyl)corrole
Research output: Contribution to journal › Journal article › Research › peer-review
High quantum yields are found for the prototype metallocorrole 1, which is readily prepared from GaCl3 and tris(pentafluorophenyl)-corrole. The crystallographic and electronic structures of 1 are reported as well as the simple generation of its π-cation radical complex by chemical oxidation and the characteristic spectroscopic features of this ion.
Original language | English |
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Journal | Angewandte Chemie - International Edition |
Volume | 39 |
Issue number | 22 |
Pages (from-to) | 4048-4051 |
Number of pages | 4 |
ISSN | 1433-7851 |
DOIs | |
Publication status | Published - 17 Nov 2000 |
- Corroles, Density functional calculations, Electronic structure, Gallium, Porphyrinoids
Research areas
ID: 240003795