Palladium-catalyzed oxidative homocoupling of pyrazole boronic esters to access versatile bipyrazoles and the flexible metal-organic framework Co(4,4′-bipyrazolate)

Research output: Contribution to journalJournal articleResearchpeer-review

  • Mercedes K. Taylor
  • Martin Juhl
  • Gul Barg Hadaf
  • Dasol Hwang
  • Ever Velasquez
  • Julia Oktawiec
  • Jonathan B. Lefton
  • Tomče Runčevski
  • Jeffrey R. Long
  • Lee, Jiwoong

A facile route to 4,4′-bipyrazole (H2bpz) and other symmetric bipyrazoles is achieved via the palladium-catalyzed homocoupling of a pyrazole boronic ester in the presence of air and water, enabling us to provide the first crystal structures and evidence of structural phase changes in the bipyrazolate-based metal-organic framework Co(bpz).

Original languageEnglish
JournalChemical Communications
Volume56
Issue number8
Pages (from-to)1195-1198
Number of pages4
ISSN1359-7345
DOIs
Publication statusPublished - 1 Jan 2020

ID: 237145466