Atmospheric chemistry of CF3O radicals: Reaction with H2O

Research output: Contribution to journal › Journal article › Research › peer-review

Standard

Atmospheric chemistry of CF3O radicals : Reaction with H2O. / Wallington, Timothy J.; Hurley, Michael D.; Schneider, William F.; Sehested, Jens; Nielsen, Ole John.

In: Journal of Physical Chemistry, Vol. 97, No. 29, 01.12.1993, p. 7606-7611.

Research output: Contribution to journal › Journal article › Research › peer-review

Harvard

Wallington, TJ, Hurley, MD, Schneider, WF, Sehested, J & Nielsen, OJ 1993, 'Atmospheric chemistry of CF3O radicals: Reaction with H2O', Journal of Physical Chemistry, vol. 97, no. 29, pp. 7606-7611.

APA

Wallington, T. J., Hurley, M. D., Schneider, W. F., Sehested, J., & Nielsen, O. J. (1993). Atmospheric chemistry of CF3O radicals: Reaction with H2O. Journal of Physical Chemistry, 97(29), 7606-7611.

Vancouver

Wallington TJ, Hurley MD, Schneider WF, Sehested J, Nielsen OJ. Atmospheric chemistry of CF3O radicals: Reaction with H2O. Journal of Physical Chemistry. 1993 Dec 1;97(29):7606-7611.

Author

Wallington, Timothy J. ; Hurley, Michael D. ; Schneider, William F. ; Sehested, Jens ; Nielsen, Ole John. / Atmospheric chemistry of CF3O radicals : Reaction with H2O. In: Journal of Physical Chemistry. 1993 ; Vol. 97, No. 29. pp. 7606-7611.

Bibtex

@article{7d5b7a6e78064c3ea72b28e16ef58e77,
title = "Atmospheric chemistry of CF3O radicals: Reaction with H2O",
abstract = "Evidence is presented that CF3O radicals react with H2O in the gas phase at 296 K to give CF3OH and OH radicals. This reaction is calculated to be exothermic by 1.7 kcal mol-1 implying a surprisingly strong CF3O-H bond energy of 120 ± 3 kcal mol-1. Results from a relative rate experimental study suggest that the rate constant for the reaction of CF3O radicals with H2O lies in the range (0.2-40) × 10-17 cm3 molecule-1 s-1. Implications for the atmospheric chemistry of CF3O radicals are discussed.",
author = "Wallington, {Timothy J.} and Hurley, {Michael D.} and Schneider, {William F.} and Jens Sehested and Nielsen, {Ole John}",
year = "1993",
month = dec,
day = "1",
language = "English",
volume = "97",
pages = "7606--7611",
journal = "Journal of Physical Chemistry",
issn = "0022-3654",
publisher = "American Chemical Society",
number = "29",

}

RIS

TY - JOUR

T1 - Atmospheric chemistry of CF3O radicals

T2 - Reaction with H2O

AU - Wallington, Timothy J.

AU - Hurley, Michael D.

AU - Schneider, William F.

AU - Sehested, Jens

AU - Nielsen, Ole John

PY - 1993/12/1

Y1 - 1993/12/1

N2 - Evidence is presented that CF3O radicals react with H2O in the gas phase at 296 K to give CF3OH and OH radicals. This reaction is calculated to be exothermic by 1.7 kcal mol-1 implying a surprisingly strong CF3O-H bond energy of 120 ± 3 kcal mol-1. Results from a relative rate experimental study suggest that the rate constant for the reaction of CF3O radicals with H2O lies in the range (0.2-40) × 10-17 cm3 molecule-1 s-1. Implications for the atmospheric chemistry of CF3O radicals are discussed.

AB - Evidence is presented that CF3O radicals react with H2O in the gas phase at 296 K to give CF3OH and OH radicals. This reaction is calculated to be exothermic by 1.7 kcal mol-1 implying a surprisingly strong CF3O-H bond energy of 120 ± 3 kcal mol-1. Results from a relative rate experimental study suggest that the rate constant for the reaction of CF3O radicals with H2O lies in the range (0.2-40) × 10-17 cm3 molecule-1 s-1. Implications for the atmospheric chemistry of CF3O radicals are discussed.

UR - http://www.scopus.com/inward/record.url?scp=0001376224&partnerID=8YFLogxK

M3 - Journal article

AN - SCOPUS:0001376224

VL - 97

SP - 7606

EP - 7611

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

SN - 0022-3654

IS - 29

ER -

ID: 228195720