Ring inversion of CH2-X-CH2-bridged peri-naphthalenes. A dynamic n.m.r. study
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Ring inversion of CH2-X-CH2-bridged peri-naphthalenes. A dynamic n.m.r. study. / Anderson, J. Edgar; Jørgensen, Flemming S.; Thomsen, Tove.
In: Journal of the Chemical Society, Chemical Communications, No. 6, 01.01.1982, p. 333-334.Research output: Contribution to journal › Journal article › Research › peer-review
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TY - JOUR
T1 - Ring inversion of CH2-X-CH2-bridged peri-naphthalenes. A dynamic n.m.r. study
AU - Anderson, J. Edgar
AU - Jørgensen, Flemming S.
AU - Thomsen, Tove
PY - 1982/1/1
Y1 - 1982/1/1
N2 - Barriers to the inversion of the six-membered rings formed by bridging the 1 - and 8-positions of naphthalene with a CH2-X-CH2 chain (X = 0,S,Se, or Te) increase along the series, O<S<Se<Te, in marked contrast with the corresponding pentamethylene heterocycles, reflecting the importance of bond angle strain during inversion.
AB - Barriers to the inversion of the six-membered rings formed by bridging the 1 - and 8-positions of naphthalene with a CH2-X-CH2 chain (X = 0,S,Se, or Te) increase along the series, O<S<Se<Te, in marked contrast with the corresponding pentamethylene heterocycles, reflecting the importance of bond angle strain during inversion.
UR - http://www.scopus.com/inward/record.url?scp=37049097305&partnerID=8YFLogxK
U2 - 10.1039/C39820000333
DO - 10.1039/C39820000333
M3 - Journal article
AN - SCOPUS:37049097305
SP - 333
EP - 334
JO - Journal of the Chemical Society D: Chemical Communications
JF - Journal of the Chemical Society D: Chemical Communications
SN - 0577-6171
IS - 6
ER -
ID: 218714388