Effects of humidity on cellulose pellets loaded with potassium titanium oxide oxalate for detection of hydrogen peroxide vapor in powders
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Effects of humidity on cellulose pellets loaded with potassium titanium oxide oxalate for detection of hydrogen peroxide vapor in powders. / Kastvig, Maria H.; Hirschberg, Cosima; Van Den Berg, Frans W. J.; Rantanen, Jukka; Andersen, Mogens L.
In: Powder Technology, Vol. 366, 2020, p. 348-357.Research output: Contribution to journal › Journal article › peer-review
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TY - JOUR
T1 - Effects of humidity on cellulose pellets loaded with potassium titanium oxide oxalate for detection of hydrogen peroxide vapor in powders
AU - Kastvig, Maria H.
AU - Hirschberg, Cosima
AU - Van Den Berg, Frans W. J.
AU - Rantanen, Jukka
AU - Andersen, Mogens L.
PY - 2020
Y1 - 2020
N2 - Hydrogen peroxide vapor in detergent and pharmaceutical powders can have detrimental effects on enzymes and active ingredients. Potassium titanium oxide oxalate (PTO) adsorbed into cellulose pellets changes color upon exposure to hydrogen peroxide vapor. TGA and DVS analyses showed that cellulose dominates the interactions of PTO-loaded pellets with humidity, while the pure PTO salt can form either a mono- or dihydrate and deliquesce above 80% RH. The mono- and dihydrate forms of PTO salt gave different changes of the surface reflectance colors after exposure to hydrogen peroxide vapor. SEM-EDX and μ-CT scans showed that titanium move towards the surface of the PTO Pellets after reaction with hydrogen peroxide further affecting the surface reflectance. It is concluded that PTO-loaded pellets are suitable for detection of hydrogen peroxide vapor at an interparticle level in powders with humidity conditions in the range of 10 to 80% RH.
AB - Hydrogen peroxide vapor in detergent and pharmaceutical powders can have detrimental effects on enzymes and active ingredients. Potassium titanium oxide oxalate (PTO) adsorbed into cellulose pellets changes color upon exposure to hydrogen peroxide vapor. TGA and DVS analyses showed that cellulose dominates the interactions of PTO-loaded pellets with humidity, while the pure PTO salt can form either a mono- or dihydrate and deliquesce above 80% RH. The mono- and dihydrate forms of PTO salt gave different changes of the surface reflectance colors after exposure to hydrogen peroxide vapor. SEM-EDX and μ-CT scans showed that titanium move towards the surface of the PTO Pellets after reaction with hydrogen peroxide further affecting the surface reflectance. It is concluded that PTO-loaded pellets are suitable for detection of hydrogen peroxide vapor at an interparticle level in powders with humidity conditions in the range of 10 to 80% RH.
KW - Cellulose pellets
KW - Detergent powder
KW - Hydrogen peroxide
KW - Potassium titanium oxide oxalate
KW - Relative humidity
U2 - 10.1016/j.powtec.2020.02.043
DO - 10.1016/j.powtec.2020.02.043
M3 - Journal article
AN - SCOPUS:85081028276
VL - 366
SP - 348
EP - 357
JO - Powder Technology
JF - Powder Technology
SN - 0032-5910
ER -
ID: 238678862