Direct observation of Mg2+ complexes in ionic liquid solutions by 31Mg β-NMR spectroscopy
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- Direct observation of Mg2+ complexes in ionic liquid solutions by 31Mg β-NMR spectroscopy
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NMR spectra of Mg2+ ions in ionic liquids were recorded using a highly sensitive variant of NMR spectroscopy known as β-NMR. The β-NMR spectra of MgCl2 in EMIM-Ac and EMIM-DCA compare favourably with conventional NMR, and exhibit linewidths of ∼3 ppm, allowing for discrimination of species with oxygen and nitrogen coordination.
Original language | English |
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Journal | Dalton Transactions |
Volume | 47 |
Issue number | 41 |
Pages (from-to) | 14431-14435 |
Number of pages | 5 |
ISSN | 1477-9226 |
DOIs | |
Publication status | Published - 2018 |
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ID: 204351880