Atmospheric lifetime of fluorotelomer alcohols

Research output: Contribution to journalJournal articlepeer-review

Standard

Atmospheric lifetime of fluorotelomer alcohols. / Ellis, DA; Martin, JW; Mabury, SA; Hurley, MD; Andersen, Mads Peter Sulbæk; Wallington, TJ.

In: Environmental Science & Technology (Washington), Vol. 37, No. 17, 01.09.2003, p. 3816-3820.

Research output: Contribution to journalJournal articlepeer-review

Harvard

Ellis, DA, Martin, JW, Mabury, SA, Hurley, MD, Andersen, MPS & Wallington, TJ 2003, 'Atmospheric lifetime of fluorotelomer alcohols', Environmental Science & Technology (Washington), vol. 37, no. 17, pp. 3816-3820. https://doi.org/10.1021/es034136j

APA

Ellis, DA., Martin, JW., Mabury, SA., Hurley, MD., Andersen, M. P. S., & Wallington, TJ. (2003). Atmospheric lifetime of fluorotelomer alcohols. Environmental Science & Technology (Washington), 37(17), 3816-3820. https://doi.org/10.1021/es034136j

Vancouver

Ellis DA, Martin JW, Mabury SA, Hurley MD, Andersen MPS, Wallington TJ. Atmospheric lifetime of fluorotelomer alcohols. Environmental Science & Technology (Washington). 2003 Sep 1;37(17):3816-3820. https://doi.org/10.1021/es034136j

Author

Ellis, DA ; Martin, JW ; Mabury, SA ; Hurley, MD ; Andersen, Mads Peter Sulbæk ; Wallington, TJ. / Atmospheric lifetime of fluorotelomer alcohols. In: Environmental Science & Technology (Washington). 2003 ; Vol. 37, No. 17. pp. 3816-3820.

Bibtex

@article{bce3dd9c48f74408b70857f5c12a7328,
title = "Atmospheric lifetime of fluorotelomer alcohols",
abstract = "Relative rate techniques were used to study the kinetics of the reactions of Cl atoms and OH radicals with a series of fluorotelomer alcohols, F(CF2CF2)(n)-CH2CH2OH (n = 2, 3, 4), in 700 Torr of N-2 or air, diluent at 296 +/- 2K. The length of the F(CF2CF2)(n)- group had no discernible impact on the reactivity of the molecule. For n = 2, 3, or 4, k(Cl + F(CF2CF2)(n)CH2CH2OH) = (1.61 +/- 0.49) x 10(-11) and k(OH + F(CF2CF2)(n)CH2CH2OH) = (1.07 +/- 0.22) x 10(-12) cm(3) molecule(-1) s(-1). Consideration of the likely rates of other possible atmospheric loss mechanisms leads to the conclusion that the atmospheric lifetime of F(CF2CF2)(n)CH2CH2OH (n greater than or equal to 2) is determined by reaction with OH radicals and is approximately 20 d.",
author = "DA Ellis and JW Martin and SA Mabury and MD Hurley and Andersen, {Mads Peter Sulb{\ae}k} and TJ Wallington",
year = "2003",
month = sep,
day = "1",
doi = "10.1021/es034136j",
language = "Udefineret/Ukendt",
volume = "37",
pages = "3816--3820",
journal = "Environmental Science & Technology",
issn = "0013-936X",
publisher = "American Chemical Society",
number = "17",

}

RIS

TY - JOUR

T1 - Atmospheric lifetime of fluorotelomer alcohols

AU - Ellis, DA

AU - Martin, JW

AU - Mabury, SA

AU - Hurley, MD

AU - Andersen, Mads Peter Sulbæk

AU - Wallington, TJ

PY - 2003/9/1

Y1 - 2003/9/1

N2 - Relative rate techniques were used to study the kinetics of the reactions of Cl atoms and OH radicals with a series of fluorotelomer alcohols, F(CF2CF2)(n)-CH2CH2OH (n = 2, 3, 4), in 700 Torr of N-2 or air, diluent at 296 +/- 2K. The length of the F(CF2CF2)(n)- group had no discernible impact on the reactivity of the molecule. For n = 2, 3, or 4, k(Cl + F(CF2CF2)(n)CH2CH2OH) = (1.61 +/- 0.49) x 10(-11) and k(OH + F(CF2CF2)(n)CH2CH2OH) = (1.07 +/- 0.22) x 10(-12) cm(3) molecule(-1) s(-1). Consideration of the likely rates of other possible atmospheric loss mechanisms leads to the conclusion that the atmospheric lifetime of F(CF2CF2)(n)CH2CH2OH (n greater than or equal to 2) is determined by reaction with OH radicals and is approximately 20 d.

AB - Relative rate techniques were used to study the kinetics of the reactions of Cl atoms and OH radicals with a series of fluorotelomer alcohols, F(CF2CF2)(n)-CH2CH2OH (n = 2, 3, 4), in 700 Torr of N-2 or air, diluent at 296 +/- 2K. The length of the F(CF2CF2)(n)- group had no discernible impact on the reactivity of the molecule. For n = 2, 3, or 4, k(Cl + F(CF2CF2)(n)CH2CH2OH) = (1.61 +/- 0.49) x 10(-11) and k(OH + F(CF2CF2)(n)CH2CH2OH) = (1.07 +/- 0.22) x 10(-12) cm(3) molecule(-1) s(-1). Consideration of the likely rates of other possible atmospheric loss mechanisms leads to the conclusion that the atmospheric lifetime of F(CF2CF2)(n)CH2CH2OH (n greater than or equal to 2) is determined by reaction with OH radicals and is approximately 20 d.

U2 - 10.1021/es034136j

DO - 10.1021/es034136j

M3 - Tidsskriftartikel

VL - 37

SP - 3816

EP - 3820

JO - Environmental Science & Technology

JF - Environmental Science & Technology

SN - 0013-936X

IS - 17

ER -

ID: 44568489